An array is an ordered list of items.  All programming languages that I am aware of include implementations of arrays.  Think first of a list of students in, say, CS 100 arranged alphabetically.  There's a first student on this alphabetic list (which is ordered alphabetically by  last names)--Aardvark, Fred.  The next student might be Adams, Susan, then Braden, William.  The last person might be Beverly Zygmunt (a real person, a former GTA--during her time here she was always the last person in the student directory).  This list would not be very useful if it was not ordered:  the Knoxville phone book is an ordered list--imagine trying to find someone's phone number if this was NOT ordered!  Programming languages vary in terms of exactly how they manage lists.  But a common way is if the list is called, say, myList, then the first element would be myList[0]--the 0th element in reality.  This is similar to for in in range(10) where i runs not from 1 to 10 but from 0 to 9.

Python has both lists and tuples.  There are differences which we will not worry about here.  There are a several ways to get lists.  One is to say, for example,

numbers = [17, 67, -2, 33, 45, 19, 106, 3]

This list has 8 elements:  numbers[0] has the value 17, numbers[1] has the value 67, numbers[7] has the value 3.  You can also create a list by reading values into it--this works a bit differently:

mylist = []       #this creates an "empty" list
for i in range(8):
      number = input("type in a value:")
      mylist.append(number)             #this adds number onto the end of the list--the list has grown by 1 value


mylist = []
for i in range(8):
      name = raw_input("type in a name:")

Here we could have asked the person running the program to tell us first how many values or names there would be:
howmany = input("how many names?")
then we could have said for i in range(howmany)  to input that number of names or values.

At any rate, we now have a list.  The list may or may not be sorted:  the list of numbers above was not sorted, and the names we read in might or might not be sorted--it would depend on what YOU did about reading them in. 
We want the smallest value to be at mylist[0], etc, and the greatest value to be at the end of the list.  In the list of numbers above, the smallest value was at numbers[2] and the largest value at numbers[6].  So obviously, this list is not yet sorted.  There are a great many different sorting routines--some are a lot better than others in terms of how long they take to sort a list.  Some are a lot better than others if your primary concern is not how long it takes to sort a list but rather how long it takes you to write the program that does the sorting.  We'll look at a couple of routines to sort our list of numbers (or names).
This is probably the easiest of the sorting routines to understand--it's also not very efficient in terms of sorting speed.  Let's first repeat the list of numbers above:
numbers = [17, 67, -2, 33, 45, 19, 106, 3]
We are going to run through this list comparing successive values (0 vs 1, 1 vs 2, 2 vs 3, etc).  We certainly want for any value of i to have numbers[i] <= numbers[i+1]:  this means that we want numbers[0] <= numbers[1], and numbers[1] <= numbers[2], etc.  So what we will do is to compare successive pairs of values, and if, say, numbers[3] > numbers[4] then we will switch/swap those two values,  so that what was numbers[4] becomes numbers[3] and vice versa.  So our main line of code will be:

for i in range(7):    #NOT 8!  see below!
      if mylist[i] > mylist[i+1]:       #we need to swap/switch values if this is true
              temp = mylist[i]              #save this value
              mylist[i] = mylist[i+1]
              mylist[i+1] = temp

if mylist[i] <= mylist[i+1] we do NOT swap values here.  Let's follow whatt happens with the list as i goes from 0 to 6:

1) i=0  numbers[0] vs numbers[1]:  17 < 67  do not switch.          17, 67, -2, 33, 45, 19, 106, 3
2) i=1  numbers[1] vs numbers[2]:  67 > -2   switch/swap            17, -2, 67, 33, 45, 19, 106, 3
3) i=2  numbers[2] vs numbers[3]:  67 > 33   switch                      17, -2, 33, 67, 45, 19, 106, 3
4) i=3  numbers[3] vs numbers[4]:  67 > 45   switch                      17, -2, 33, 45, 67, 19, 106, 3
5) i=4  numbers[4] vs numbers[5}:  67 > 19  switch                       17, -2, 33, 45, 19, 67, 106, 3
6) i=5  numbers[5] vs numbers[6]:  67 < 106 do not switch          17, -2, 33, 45, 19, 67, 106, 3
7) i-6  numbers[6] vs numbers[7]:  106 > 3  switch                       17, -2, 33, 45, 19, 67, 3, 106

is this list sorted? NO!  have we made progress?  Well, note that the largest number--106--is at the end of the list.  Smaller numbers have inched toward the front of the list (which is why it's called the bubble sort--small numbers bubble up slowly toward the front).  So we need to go through the list again--try it!  The list would now appear as -2, 17, 33, 19, 45, 3, 67, 106 so the 2nd largest value is now in the next-to-last position.  The smallest number is at the front, but the next smallest value has a ways to go to reach its proper slot.  So here's the overall code to make things work:

flag = 1    #a 1 here says we assume the list is not fully sorted
while flag > 0:            #continue until fully sorted
       flag = 0                 # we're hoping things are all sorted.......
       for i in range(7):
              if mylist[i] > mylist[i+1]:         #bah! we found something out of order--swap values
                      temp = mylist[i]
                      mylist[i] = mylist[i+1]
                      mylist[i+1] = temp
                      flag = 1                             #this means we found something not sorted in the list

print mylist                                           #prints sorted list

So what this does is we keep making passes through the list.  Before each pass we set the flag to 0 indicating that nothing is out of order--YET!  If we ever do find values that need swapping, flag gets set to 1 meaning we're going to need another pass through the list.  Suppose when we drop out of the for loop flag is still 0:  this means that we didn't need to swap any values--in each case numbers[1] was <= numbers[i+1], and so everything is sorted, and since flag is still 0 at the end of the for loop, this also drops us out of the while loop, so we're done, and we can print the list.